Tafatirka xogta jirka
1. Hanti: caddaan ilaa casaan casaan ah, midab madow marka lagu kaydiyo hawada muddo dheer.
2. Cufnaanta (g/ml, 20/4℃): 1.181.
3. Cufnaanta qaraabada (20℃, 4℃): 1.25. 4.
Barta dhalaalka (ºC): 122 ~ 123. 5.
Barta karkarinta (ºC, cadaadiska atmospheric) :285 ~ 286. 6.
6. dhibic (ºC): 153. 7. milmayn: aan milmayn.
Solubility: aan lagu milmin biyo qabow, ku milmay biyo kulul, ethanol, ether, chloroform, benzene, glycerin iyo lye [1].
Tafatirka xogta
1. Tusiyaha dib u celinta Molar: 45.97
2. Mugga molar (cm3/mol): 121.9
3, mugga gaarka ah ee Isotonic (90.2K): 326.1
4. Xiisadda dusha sare (3.0 dyne/cm) :51.0
5, Saamiga Polarization (0.5 10-24cm3): 18.22 [1]
Dabeecada iyo xasiloonida
wax ka beddel
1. Toxicology waxay la mid tahay phenol, waana daxalka ka xoog badan. Si xoog leh u xanaaqa maqaarka. Si fudud ayaa loo nuugo maqaarka. Sun ku ah wareegga dhiigga iyo kelyaha. Intaa waxaa dheer, waxay keeni kartaa dhaawaca lafaha. Inkastoo aan la ogeyn inta ay le'eg tahay tirada dhimashada, waxaa jiray kiisas dhimasho ah oo ka yimid isticmaalka jirka ee 3 ilaa 4g. Qalabka wax-soo-saarka waa in la xidhaa oo aan dareerin, waana in lagu dhaqo wakhti ku habboon haddii maqaarka lagu rusheeyo. Aqoon-is-weydaarsiyada waa in la sii daayaa, qalabkuna waa inuu noqdaa mid hawada ku xiran. Hawl-wadeenadu waa inay xidhaan qalab ilaalin ah.
2. Dabci kara, midabka kaydinta dheer ayaa si tartiib tartiib ah u madoobanaya, hawadu degan tahay, laakiin marka qorraxdu soo baxdo si tartiib tartiib ah ayey u madoobaataa. Sublimation by kululaynta, oo leh ur phenol xanaaqa.
3. ku jira gaaska qiiqa. 4.
4. Xalka aqueous wuxuu u noqdaa cagaar leh chloride ferric [1].
Habka kaydinta
wax ka beddel
1. Lagu dahaadhay baco, jawaanno ama bacaha tolmada leh, miisaanka saafiga ah 50kg ama 60kg kiishkaba.
2. Kaydinta iyo gaadiidku waa inay ahaadaan kuwo aan dabci karin, qoyaan-celin, ka-hortagga soo-gaadhista. Lagu kaydiyaa meel engegan oo hawo leh. Kaydi oo rarid si waafaqsan xeerarka walxaha guban iyo sunta ah.
Habka synthetic
wax ka beddel
1. Waxa laga sameeyaa naphthalene iyada oo loo marayo sulfonation iyo alkali dhalaalay. dhalaalidda alkali sulfonation waa hab si weyn loo isticmaalo gudaha iyo dibadda, laakiin daxalka waa halis, kharashka waa badan yahay iyo isticmaalka oksijiinta noolaha biyaha wasakh ah waa mid sare. Habka 2-isopropylnaphthalene ee ay soo saartay Shirkadda American Cyanamid waxay qaadataa naphthalene iyo propylene sida alaabta ceeriin, waxayna soo saartaa 2-naphthol iyo acetone isku mar, taas oo la mid ah kiiska phenol ee habka isopropylbenzene. Kootada isticmaalka alaabta ceeriin: 1170kg/t naphthalene ganaax, 1080kg/t sulfuric acid, 700kg/t soodhaha caustic adag.
2. Kuleyli naphthalene-ka dhalaalaysa ilaa 140 ℃, oo leh saamiga naphthalene:sulfuric acid = 1:1.085 (molar ratio), sulfuric acid 98% 20min, iyo sulfuric acid 98% 20min.
Dareen-celinta waxay dhammaan doontaa marka maadada 2-naphthalenesulfonic acid ay gaarto in ka badan 66% iyo wadarta guud ee acidity waa 25% -27%, ka dibna falcelinta hydrolysis waxaa lagu sameyn doonaa 160 ℃ 1h, naphthalenes bilaash ah ayaa lagu afuufin doonaa uumiga biyaha. at 140-150 ℃, ka dibna cufnaanta qaraabo ee 1.14 naphthalenes waxaa lagu dari doonaa si tartiib ah iyo si siman at 80-90 ℃ ka hor. Xalka sodium sulfite waa dhexdhexaad ilaa warqadda tijaabada cas ee Kongo aysan isbeddelin buluug. Falcelinta gaaska sulfur dioxide ee wakhtiga ku habboon la soo saaro uumiga, alaabada dhexdhexaadinta ayaa la qaboojiyey ilaa 35 ~ 40 ℃ qaboojiyaha qaboojiyaha, nuugaya kiristaalo shaandhada leh 10% biyo milix ah, qalalan, oo lagu daray gobolka dhalaalay ee 98% sodium hydroxide at 300 ~ 310 ℃, walaaqaya oo joogteeyo 320 ~ 330 ℃, si ay saldhigga sodium 2-naphthalene sulfonate la isku daray si 2-naphthol sodium, ka dibna isticmaal biyo kulul si ay u milmaan dhalaalka salka, ka dibna u gudubto xagga sare dhexdhexaadiye sulfur dioxide ka dhashay falcelinta, falcelinta acidification at 70 ~ 80 ℃ ilaa phenolphthalein ahaa midab lahayn. Alaabta acidification-ku waxay noqon doonaan lakabyo joogto ah, lakabka sare ee dareeraha kululaynta si karkaraya, taagan, qaybsan lakabka aqueous, alaabta ceeriin ee 2-naphthol marka hore kulaylka fuuqbaxa, ka dibna distillation decompression, noqon kartaa alaabta saafi ah.
3. Habka soo saarista iyo crystallization si looga saaro 1-naphthol ee 2-naphthol. Isku qas 2-naphthol iyo biyo qayb ahaan iyo kulayl ilaa 95 ℃, marka 2-naphthol la dhalaaliyo, walaaq isku dar ah si xoog leh oo hoos u dhig heerkulka ilaa 85℃ ama wax ka badan, qabooji sheyga slurry ee kareemka leh heerkulka qolka oo shaandh. Waxa ku jira 1-naphthol waxaa lagu raad raaci karaa falanqaynta daahirsanaanta. 4.
Waxa laga soo saaray 2-naphthalenesulfonic acid by alkali dhalaalay [2].
Habka kaydinta
wax ka beddel
1. Lagu dahaadhay baco, jawaanno ama bacaha tolmada leh, miisaanka saafiga ah 50kg ama 60kg kiishkaba.
2. Kaydinta iyo gaadiidku waa inay ahaadaan kuwo aan dabci karin, qoyaan-celin, ka-hortagga soo-gaadhista. Lagu kaydiyaa meel engegan oo hawo leh. Kaydi oo rarid si waafaqsan xeerarka walxaha guban iyo sunta ah.
Isticmaal
wax ka beddel
1. Waxyaabaha muhiimka ah ee alaabta ceeriin ee dabiiciga ah iyo dhexdhexaadiyeyaasha dheeha, oo loo isticmaalo soo saarista tartaric acid, butyric acid, β-naphthol-3-carboxylic acid, oo loo isticmaalo soo saarista antioxidant butyl, antioxidant DNP iyo antioxidants kale, pigments organic iyo fungicides.
2. Loo isticmaalo sidii reagement si loo go'aamiyo sulfonamide iyo amines caraf udgoon iyadoo la isticmaalayo chromatography lakabka khafiifka ah. Waxa kale oo loo isticmaalaa isku-dhafka organic.
3. Waxaa loo isticmaalaa si loo hagaajiyo polarization cathodic, sifeeyo crystallization iyo in la yareeyo xajmiga daloolka ee dahaadhida aashitada. Sababo la xiriira dabeecadda hydrophobic ee alaabtan, kakoobnaanta xad dhaafka ah waxay keeni doontaa uumi jelatin iyo roobab, taasoo keentay in ay xadhkaha goostaan.
4. Inta badan loo isticmaalo wax soo saarka ee orange acid Z, acid orange II, acid madow ATT, acid mordant madow T, acid mordant madow A, mordant acid madow R, acid adag pink B, kakan acid casaan brown BRRW, acid adag madow WAN , midabka phenol AS, midabka phenol AS-D, midabka phenol AS-OL, phenol midabka AS-SW, orange dhalaalaya firfircoon X-GN, orange dhalaalaya firfircoon K-GN, casaan firfircoon K-1613, casaan firfircoon K-1613, firfircoon orange dhalaalaya X-GN, orange dhalaalaya firfircoon K-GN. Purple Purple BL, Dhexdhexaad Madow BGL, Toos ah Copper Salt Buluug 2R, Iftiinka Qorraxda Tooska ah ee Buluuga B2PL, Buluugga Tooska ah RG, Tooska buluuga ah RW iyo midabyo kale [2].
Waqtiga boostada: Seb-10-2020